New Module for deriving Maxwell's Four Relations

The four Maxwell’s relations are important equations employed mainly in the field of chemical engineering to perform certain computations involving the four thermodynamic potentials, temperature (T), pressure (P), volume (V) and entropy (S) In chemical engineering, the method for deriving these four relations is by employing the Gibbs-Duhem-Margules approach which is somewhat tedious and lengthy.
In this paper, we shall explore another module in the derivation of these four
Maxwell’s relations by employing certain simple techniques with our basis as the mathematical equation of the first law of thermodynamics.

Inhaltsverzeichnis (Table of Contents)

• Abstract
• Introduction
• Alfred Addo-Yobo's derivation:
• Interchange technique:
• Sign application:

Zielsetzung und Themenschwerpunkte (Objectives and Key Themes)

This paper aims to provide an alternative method for deriving the four Maxwell's relations, which are fundamental equations used in chemical engineering. The paper explores a derivation based on the first law of thermodynamics, avoiding the often lengthy Gibbs-Duhem-Margules approach.

• Derivation of Maxwell's relations
• Application of the first law of thermodynamics
• Use of partial differentials
• Introduction of a novel interchange technique
• Development of a rule for applying signs to Maxwell's relations

Zusammenfassung der Kapitel (Chapter Summaries)

• The abstract provides a brief overview of the paper's purpose and key concepts. It highlights the importance of Maxwell's relations in chemical engineering and introduces the alternative derivation method employed.
• The introduction lays out the foundation of the paper's approach, which is rooted in the first law of thermodynamics. It presents the mathematical equation of the first law and defines the relevant thermodynamic potentials.
• The section "Alfred Addo-Yobo's derivation" details the proposed method for deriving the four Maxwell's relations. It begins by applying partial differentials to the first law equation and establishes a crucial intermediate relation.
• The "Interchange technique" section explains the process of using the derived intermediate relation to obtain the four incomplete Maxwell's relations. This technique involves systematic manipulation of the parameters in the relation.
• The "Sign application" section introduces a rule, known as the Addo-Yobo rule, for applying the correct signs to the incomplete Maxwell's relations. This rule involves analyzing the progression of alphabets in the parameters and adding negative signs based on the direction of arrows placed on diagonal lines.

Schlüsselwörter (Keywords)

The primary keywords and focus topics of this work include Maxwell's relations, the first law of thermodynamics, chemical engineering, Gibbs-Duhem-Margules equations, and derivation. This research explores alternative methods for deriving Maxwell's relations, emphasizing the importance of these equations in the field of chemical engineering.

Details

• College: Kwame Nkrumah University of Science and Technology
• Author: Alfred Addo-Yobo (Author)
• Publication Year: 2013
• Pages: 6
• Catalog Number: V264225
• ISBN (eBook): 9783656537526
• ISBN (Book): 9783656575054
• Language: English
• Tags: module maxwell four relations